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dc.contributor.authorMeisak, Darya
dc.contributor.authorMacutkevic, Jan
dc.contributor.authorSelskis, Algirdas
dc.contributor.authorKuzhir, Polina
dc.contributor.authorBanys, Juras
dc.date.accessioned2021-04-07T11:30:34Z
dc.date.available2021-04-07T11:30:34Z
dc.date.issued2021
dc.identifier.urihttps://erepo.uef.fi/handle/123456789/24758
dc.description.abstractThe dielectric/electric properties of the Ni@C (carbon-coated Ni)/epoxy composites and Ni@C/MWCNTs (multi-walled carbon nanotubes)/epoxy composites loaded with fixed MWCNTs amount just below the percolation threshold (0.09 vol.%) and Ni@C at different concentrations up to 1 vol.% were investigated in broad frequency (20 Hz–40 GHz) and temperature (30 K–500 K) regions. In composites with the only Ni@C nanoparticles, the electrical percolation threshold was determined between 10 and 15 vol.%. Above the percolation threshold the dielectric permittivity (ε’) and the electrical conductivity (σ) of the composites loaded with Ni@C only are high enough, i.e., ε’ = 105 and σ = 0.6 S/m at 100 Hz for composites with 30 vol.% Ni@C, to be used for electromagnetic shielding applications. The annealing to 500 K was proved to be an effective and simple tool to decrease the percolation threshold in epoxy/Ni@C composites. For hybrid composites series an optimal concentration of Ni@C (0.2 vol.%) was determined, leading to the conductivity absolute values several orders of magnitude higher than that of a composite filled with MWCNTs only. The synergy effects of using both fillers have been discussed. Below room temperature the electrical transport is mainly governed by epoxy resin compression in all composites, while the electron tunnelling was observed only in hybrid composites below 200 K. At higher temperatures (above 400 K), in addition to the nanoparticles redistribution effects, the electrical conductivity of epoxy resin makes a significant contribution to the total composite conductivity. The dielectric relaxation spectroscopy allows estimating the nanoparticles distributions in polymer matrix and could be used as the non-destructive and fast alternate to microscopy techniques for general polymer composite fabrication control.
dc.language.isoenglanti
dc.publisherMDPI AG
dc.relation.ispartofseriesNanomaterials
dc.relation.urihttp://dx.doi.org/10.3390/nano11020555
dc.rightsCC BY http://creativecommons.org/licenses/by/4.0/
dc.subjectcarbon nanotubes
dc.subjectcarbon-coated Ni
dc.subjectepoxy
dc.subjectelectrical properties
dc.subjectconductivity
dc.subjectrelaxation time
dc.titleDielectric Relaxation Spectroscopy and Synergy Effects in Epoxy/MWCNT/Ni@C Composites
dc.description.versionpublished version
dc.contributor.departmentDepartment of Physics and Mathematics, activities
uef.solecris.id77200228en
dc.type.publicationTieteelliset aikakauslehtiartikkelit
dc.rights.accessrights© 2021 by the authors
dc.relation.doi10.3390/nano11020555
dc.description.reviewstatuspeerReviewed
dc.publisher.countrySveitsi
dc.relation.articlenumber555
dc.relation.issue2
dc.relation.volume11
dc.rights.accesslevelopenAccess
dc.type.okmA1
uef.solecris.openaccessOpen access -julkaisukanavassa ilmestynyt julkaisu


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