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dc.contributor.authorPhilip, Anish
dc.contributor.authorAnkudze, Bright
dc.contributor.authorPakkanen, Tuula T
dc.date.accessioned2018-05-16T12:26:38Z
dc.date.available2018-05-16T12:26:38Z
dc.date.issued2018
dc.identifier.urihttps://erepo.uef.fi/handle/123456789/6612
dc.description.abstractLarge-sized gold nanoparticles (AuNPs) were synthesized with a new polyethylenimine − assisted seed − mediated method for surface-enhanced Raman scattering (SERS) studies. The size and polydispersity of gold nanoparticles are controlled in the growth step with the amounts of polyethylenimine (PEI) and seeds. Influence of three silicon oxide supports having different surface morphologies, namely halloysite (Hal) nanotubes, glass plates and inverse opal films of SiO2, on the performance of gold nanoparticles in Raman scattering of a 4-aminothiophenol (4-ATP) analyte was investigated. Electrostatic interaction between positively charged polyethylenimine-capped AuNPs and negatively charged surfaces of silicon oxide supports was utilized in fabrication of the SERS substrates using deposition and infiltration methods. The Au-photonic crystal of the three SERS substrate groups is the most active one as it showed the highest analytical enhancement factor (AEF) and the lowest detection limit of 1x10−8 M for 4-ATP. Coupling of the optical properties of photonic crystals with the plasmonic properties of AuNPs provided Au-photonic crystals with the high SERS activity. The AuNPs clusters formed both in the photonic crystal and on the glass plate are capable of forming more hot spots as compared to sparsely distributed AuNPs on Hal nanotubes and thereby increasing the SERS enhancement.
dc.language.isoenglanti
dc.publisherElsevier BV
dc.relation.ispartofseriesApplied Surface Science
dc.relation.urihttp://dx.doi.org/10.1016/j.apsusc.2018.03.042
dc.rightsCC BY-NC-ND https://creativecommons.org/licenses/by-nc-nd/4.0/
dc.subjectgold nanoparticles
dc.subjectpolyethylenimine
dc.subjectseed-mediated synthesis
dc.subjectSERS
dc.subjecthalloysite nanotubes
dc.subjectphotonic crystals
dc.titlePolyethylenimine-assisted seed-mediated synthesis of gold nanoparticles for surface-enhanced Raman scattering studies
dc.description.versionfinal draft
dc.contributor.departmentDepartment of Chemistry, activities
uef.solecris.id54105951en
dc.type.publicationTieteelliset aikakauslehtiartikkelit
dc.rights.accessrights© Elsevier B.V.
dc.relation.doi10.1016/j.apsusc.2018.03.042
dc.description.reviewstatuspeerReviewed
dc.format.pagerange243-252
dc.relation.issn0169-4332
dc.relation.volume444
dc.rights.accesslevelopenAccess
dc.type.okmA1
uef.solecris.openaccessEi


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